D) Six electron pairs

 

If there are six electron pairs on the central atom, the angle between the bonds is 90o.

 

 

 

Molecules which adopt this shape are said to be OCTAHEDRAL.

 

E.g. SF6

 


If there are 4 bonding pairs and 2 lone pairs, the bonded pairs are at 90o in the plane and the lone pairs at 180o. The angles are still exactly 90o because the lone pairs are opposite each other so their repulsion cancels out.

 

 

Molecules which adopt this shape are said to be SQUARE PLANAR.

 

E.g. XeF4, ClF4-

 

SUMMARY OF MOLECULAR SHAPES

    Valence shell electron pairs Bonding pairs Lone pairs shape Bond Angle (o)
          LINEAR  
          TRIGONAL PLANAR  
          BENT 115 - 118

 

          TETRAHEDRAL 109.5
          TRIGONAL PYRAMIDAL  
          BENT 104.5
          TRIGONAL BIPYRAMIDAL 90 and 120
          OCTAHEDRAL  
          SQUARE PLANAR  


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